摘要
The title complex was synthesized by reaction of taurine salicylic schiff base(TSSB), O phenanthroline(phen) and cupric acetate in water ethanol solution. The crystal structure was determined by X ray diffraction method and the chemical formula weight of the complex is 498.00. And the crystal structure belongs to orthorhombic system with space group Pbcn and cell parameters: a=31.072(4)?, b=12.8909(18)?, c=10.3478(14)?; V=4144.7(10)?3,Z=8,Dc=1.596Mg·m-3,μ=1.197mm-1 and F(000)=2048. The compound is an one dimensional chain complex of infinite length connecting with hydrogen bonds. The Cu? was coordinated by two oxygen atoms and three nitrogen while the O atoms of Ac groups did not coordinate. At the same time the Cu?formed a distorted tragonal cone. Besides the capacities of coordination to Cu? of atoms were discussed.
The title complex was synthesized by reaction of taurine salicylic schiff base(TSSB), O phenanthroline(phen) and cupric acetate in water ethanol solution. The crystal structure was determined by X ray diffraction method and the chemical formula weight of the complex is 498.00. And the crystal structure belongs to orthorhombic system with space group Pbcn and cell parameters: a=31.072(4)?, b=12.8909(18)?, c=10.3478(14)?; V=4144.7(10)?3,Z=8,Dc=1.596Mg·m-3,μ=1.197mm-1 and F(000)=2048. The compound is an one dimensional chain complex of infinite length connecting with hydrogen bonds. The Cu? was coordinated by two oxygen atoms and three nitrogen while the O atoms of Ac groups did not coordinate. At the same time the Cu?formed a distorted tragonal cone. Besides the capacities of coordination to Cu? of atoms were discussed.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2002年第5期497-500,共4页
Chinese Journal of Inorganic Chemistry
