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邻苯二胺合钴氧合反应的研究 Ⅰ水溶液中配合物及其氧合配合物稳定常数的测定 被引量：5

The Study on Oxygenation of o-Phenylenediamine Cobalt Complexes Ⅰ Determination of the Stability Constants of Complexes and Oxygenated Complexes in Aqueous Solution
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摘要 In this paper, the stability constants of the o Phdn Co complexes and oxygenated complexes were determined by pH potentiometry for the first time. The determined method was verified with the known o Phdn Cu system by comprising the stability constants obtained from experiment results with those in literatures. The calculated results of oxygenated complexes were confirmed by spectrophotometry. All the results are agreed very well, which show the correctness of the determination. In this paper, the stability constants of the o Phdn Co complexes and oxygenated complexes were determined by pH potentiometry for the first time. The determined method was verified with the known o Phdn Cu system by comprising the stability constants obtained from experiment results with those in literatures. The calculated results of oxygenated complexes were confirmed by spectrophotometry. All the results are agreed very well, which show the correctness of the determination.
作者 岳凡 王吉德 张翼 宋启军 李兴寿
机构地区 新疆大学化学系
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2002年第5期489-492,共4页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.29962003)
关键词 氧载体 邻苯二胺 钴 氧合作用 配位常数 配合物 氧合反应 稳定常数 oxygen carrier o phenylenediamine cobalt oxygenation coordination constants
分类号 O614.812 [理学—无机化学]
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参考文献1

二级参考文献5

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共引文献6

同被引文献35

  • 1杨红伟,岳凡,陈玲,封顺,王吉德,刘爱华,陈华梅.固相反应合成丙二胺合钴氧合性能的研究[J].无机化学学报,2004,20(12):1421-1425. 被引量：4
  • 2贾士儒,李小明,包志泉,刘澄.氧载体强化传氧的研究Ⅰ[J].天津轻工业学院学报,1994,9(1):7-12. 被引量：8
  • 3肖芙蓉,王吉德,岳凡,武荣兰,陈鹭.苯甲醛缩三乙烯四胺Schiff碱Co(Ⅱ)配合物固相合成及氧合性能研究[J].无机化学学报,2006,22(7):1293-1298. 被引量：5
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引证文献5

二级引证文献12

无机化学学报
2002年 第5期

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