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铀酰萃取剂双亚砜的合成及其微胶囊萃取铀性能的研究 被引量:3

Syntheses of disulfoxides and the studies on the extractants contained by microcapsules for uranyl
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摘要 A series of disulfoxides which have not been reported previously were synthesized by oxidation of sulfide with nitric acid and characterized by elemental analysis,IR and NMR spectroscopy.Microcapsules(MC) containing tri n butyl phosphate(TBP) and disulfoxides were prepared by interface condensation polymerization,and uranyl in aquous solution were extraced with the MC.The results show that extracting abilities of disulfoxides for uranyl are superior to that of TBP,and that of di (phenyl sulphinyl) ethan is the best one among them. A series of disulfoxides which have not been reported previously were synthesized by oxidation of sulfide with nitric acid and characterized by elemental analysis,IR and NMR spectroscopy.Microcapsules(MC) containing tri n butyl phosphate(TBP) and disulfoxides were prepared by interface condensation polymerization,and uranyl in aquous solution were extraced with the MC.The results show that extracting abilities of disulfoxides for uranyl are superior to that of TBP,and that of di (phenyl sulphinyl) ethan is the best one among them.
出处 《化学研究与应用》 CAS CSCD 北大核心 2002年第2期188-190,共3页 Chemical Research and Application
基金 江苏省有机化学重点实验室资助项目 (980 2 3 76)
关键词 双亚砜 合成 微胶囊 铀酰离子 萃取 萃取剂 萃取性能 disulfoxide synthesis microcapsule extraction of uranyl
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