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Co/HZSM-5催化剂中Co相态和价态的表征 被引量:5

Charaterization of the Phase and Valency State of Co on Co/HZSM-5 Catalysts
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摘要 The phase and valency state of cobalt species on Co/HZSM 5 catalysts containing 1 0% to 10 0% cobalt were characterized by XRD, TPR and DRS technique. It was found that cobalt species on Co/HZSM 5 may exist in the phases of Co 3O 4, CoO, CoAl 2O 4 spinel, exchanged Co or metal Co at different calcination and reduction temperature, and CoAl 2O 4 spinel is difficult to be reduced. The phase and valency state of cobalt species on Co/HZSM 5 catalysts containing 1 0% to 10 0% cobalt were characterized by XRD, TPR and DRS technique. It was found that cobalt species on Co/HZSM 5 may exist in the phases of Co 3O 4, CoO, CoAl 2O 4 spinel, exchanged Co or metal Co at different calcination and reduction temperature, and CoAl 2O 4 spinel is difficult to be reduced.
作者 张强 汪晓东
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2002年第1期129-131,共3页 Chemical Journal of Chinese Universities
关键词 Co/HZSM-5催化剂 相态 价态 表征 苯乙烯 合成 分子筛 负载型催化剂 Co/HZSM 5 catalyst Phase state Valency state Characterization
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