混杂配体金属簇合物的分子振动光谱与结构

Spectra and Structure of the Metal Cluster Complexes with Mixed Ligands

由于原子簇化合物在催化 ,生物活性 ,功能材料等方面所呈现的重要性 ,使其成为无机和物理化学最重要的研究领域之一。文章中用谱学方法对一些具有混配体的过渡金属簇合物的结构及其两者之间的关系进行研究。

The cluster compounds become one of the most important fields in inorganic chemistry and physical chemistry study becasuse of their character and potential use in catalyzer., functional material, etc. The IR and Raman spectra of the crystals with two different ligands, one is easily deoxidized and the other is easily oxidized, have been investigated, and the relationship between the spectrum and the structure has been discussed as well.