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红外光谱法测定O-100mol%D_2O浓度 被引量:2

THE DETERMINATION OF 0—100mol% CONCENTRATION HEAVY WATER BY INFRARED SPECTROPHOTOMETRY
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摘要 一、前言重水作为稳定性同位素广泛地应用在农业、生物、医学和化学领域中。高浓重水是性能很好的反应堆材料,既是冷却剂又是减速剂。 Analysis of 0—100mol% D_2O concentration with infrared spectrophoto meter is based on the fact that heavy water of different concentration has different characteristic spectrum of infrared absorption. The deter mination wave numbers are 3400cm^(-1) for high concentrations of heavy water, 3040cm^(-1), 1900cm^(-1), 1550cm^(-1) and 1450cm^(-1) for medium concentrations of heavy water; 2500cm^(-1) for low concentrations of heavy water. Utilizing heavy water sample of known concentration to draw a standard curve, unknown sample was deter mined by external reference method. Precisions of the method are ±0.02 mol% D_2O for high concentrations, ±1mol% D_2O for medium concentrations, ±0.05mol% D_2O for low concentrations.
出处 《同位素》 CAS 北大核心 1991年第2期107-113,共7页 Journal of Isotopes
关键词 重水 浓度 红外光谱 concentration of heavy water, infrared spectrophotometry.
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