NH_2自由基电子激发态荧光寿命的理论计算

Theoretical investigation on the emission lifetime of electrical excited state for NH_2 radical

采用大振幅弯曲振动哈密顿,同时考虑到Renner-Teller效应,理论上计算了NH2自由基A珟2A1电子激发态荧光寿命,计算值与实验值符合较好。

Based on the large amplitude bending vibratinal Hamitonian and the Renner-Teller effect describing vibronic interaction, the emission lifetime of the electronic excited state has been calculated. The calculation results are in good agreement with experiment.