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含叠氮酸根的锰(Ⅱ)配合物的合成与晶体结构 被引量：2

Synthesis and Crystal Structures of Manganese(Ⅱ) Complexes Containing the Azide Anion
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摘要 Two new mononuclear Mn ￡"complexes Mn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡2￡¨￡±￡(c)andMn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡¨H￡2O￡(c)ClO4·H2 O￡¨￡2￡(c)have been synthesized and structura lly characterized,where phen is ￡±￡?￡±￡°￡-phenanthroline￡(r)Complex1crystallizes in theP1pace group,with lattice parameters a￡1/2￡?￡(r)￡±￡?￡?￡?￡¨￡2￡(c)|!￡?b￡1/2￡±￡±￡(r)￡±￡2￡±￡?￡¨￡2￡(c)|!￡?c￡1/2￡±￡2￡(r)6￡?￡?￡±￡¨￡2￡(c)|!￡?|á￡1/2￡?￡3￡(r)￡μ￡μ￡?￡¨￡3￡(c)??￡?|?￡1/2￡?￡2￡(r)28￡*￡¨￡3￡(c)??￡?|?￡1/2￡*￡3￡(r)6￡¨￡3￡(c)??￡?V￡1/2￡±￡°￡1￡2￡(r)￡*￡¨￡′￡(c)|!￡3￡?Dc￡1/2￡±￡(r)￡μ￡±￡?Mg ?¤m￡-￡3￡?Z ￡1/22,F(000￡(c)￡1/2￡μ￡±￡°￡?R￡±￡1/2￡°￡(r)￡°￡?￡2￡°￡?w R￡2￡1/2￡°￡(r)0958(based on F￡2 ￡(c)￡?S￡1/2￡°￡(r)￡1￡?￡±￡(r)Complex2crystallizes in theP1space group,with lattice parameters a￡1/2￡?￡(r)￡?￡μ￡′￡3￡¨￡2￡(c)|!￡?b￡1/2￡?￡(r)￡1￡*￡?￡*￡¨￡2￡(c)|!￡?c￡1/2￡±￡*￡(r)5915￡¨￡′￡(c)|!￡?|á￡1/2￡1￡3￡(r)￡3￡1￡1￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡2￡(r)￡?￡°￡?￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡?￡(r)23￡′￡¨￡3￡(c)??￡?V￡1/2￡±￡2￡?￡?￡(r)￡*￡¨￡′￡(c)? ￡3 ￡?Dc￡1/2￡±￡(r)￡μ￡μ￡2Mg ?¤m￡-￡3￡?Z ￡1/2￡2￡?F￡¨￡°￡°￡°￡(c)￡1/2606,R!? ￡1/2￡°￡(r)067￡2￡?w R ￡2 ￡1/2￡°￡(r)1781(based on F2 ￡(c)￡?S￡1/2￡±￡(r)￡°￡′￡*￡(r)In complex1,the Mn atom is coordinated by six nit rogen atoms of two phen molecules and two N 3- ions with the Mn￡-N distances ranging from ￡2￡(r)￡±￡′￡2￡¨￡′￡(c)to ￡2￡(r)318(4￡(c)|!￡(r)The coordinated phen molecules of the adjacent Mn ￡¨phen￡(c) ￡2 ￡¨N ￡3 ￡(c) 2 moieties experienceπ-πstacking which is responsible for th e crystal packing￡(r)In complex2,the Mn atom is coordinated by five ni trogen atoms of two phen molecules an d one N 3- ion with the Mn￡-N distances ranging from ￡2￡(r)￡±￡μ￡2￡¨￡μ￡(c)to ￡2￡(r)291(5￡(c)|!￡(r)The approximately octahedral environment was completed by the oxygen atom of the coordinated water molecule with the Mn?O distance of ￡2￡(r)￡±￡?￡°￡¨￡μ￡(c)?￡(r)The hydrate water molecule is hydrogen-bonded to one of the O ato ms of free ClO ￡′￡- anion￡(r) Two new mononuclear Mn ￡'complexes Mn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡2￡¨￡±￡(c)andMn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡¨H￡2O￡(c)ClO4·H2 O￡¨￡2￡(c)have been synthesized and structura lly characterized,where phen is ￡±￡?￡±￡°￡-phenanthroline￡(r)Complex1crystallizes in theP1pace group,with lattice parameters a￡1/2￡?￡(r)￡±￡?￡?￡?￡¨￡2￡(c)|!￡?b￡1/2￡±￡±￡(r)￡±￡2￡±￡?￡¨￡2￡(c)|!￡?c￡1/2￡±￡2￡(r)6￡?￡?￡±￡¨￡2￡(c)|!￡?|á￡1/2￡?￡3￡(r)￡μ￡μ￡?￡¨￡3￡(c)??￡?|?￡1/2￡?￡2￡(r)28￡*￡¨￡3￡(c)??￡?|?￡1/2￡*￡3￡(r)6￡¨￡3￡(c)??￡?V￡1/2￡±￡°￡1￡2￡(r)￡*￡¨￡′￡(c)|!￡3￡?Dc￡1/2￡±￡(r)￡μ￡±￡?Mg ?¤m￡-￡3￡?Z ￡1/22,F(000￡(c)￡1/2￡μ￡±￡°￡?R￡±￡1/2￡°￡(r)￡°￡?￡2￡°￡?w R￡2￡1/2￡°￡(r)0958(based on F￡2 ￡(c)￡?S￡1/2￡°￡(r)￡1￡?￡±￡(r)Complex2crystallizes in theP1space group,with lattice parameters a￡1/2￡?￡(r)￡?￡μ￡′￡3￡¨￡2￡(c)|!￡?b￡1/2￡?￡(r)￡1￡*￡?￡*￡¨￡2￡(c)|!￡?c￡1/2￡±￡*￡(r)5915￡¨￡′￡(c)|!￡?|á￡1/2￡1￡3￡(r)￡3￡1￡1￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡2￡(r)￡?￡°￡?￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡?￡(r)23￡′￡¨￡3￡(c)??￡?V￡1/2￡±￡2￡?￡?￡(r)￡*￡¨￡′￡(c)? ￡3 ￡?Dc￡1/2￡±￡(r)￡μ￡μ￡2Mg ?¤m￡-￡3￡?Z ￡1/2￡2￡?F￡¨￡°￡°￡°￡(c)￡1/2606,R!? ￡1/2￡°￡(r)067￡2￡?w R ￡2 ￡1/2￡°￡(r)1781(based on F2 ￡(c)￡?S￡1/2￡±￡(r)￡°￡′￡*￡(r)In complex1,the Mn atom is coordinated by six nit rogen atoms of two phen molecules and two N 3- ions with the Mn￡-N distances ranging from ￡2￡(r)￡±￡′￡2￡¨￡′￡(c)to ￡2￡(r)318(4￡(c)|!￡(r)The coordinated phen molecules of the adjacent Mn ￡¨phen￡(c) ￡2 ￡¨N ￡3 ￡(c) 2 moieties experienceπ-πstacking which is responsible for th e crystal packing￡(r)In complex2,the Mn atom is coordinated by five ni trogen atoms of two phen molecules an d one N 3- ion with the Mn￡-N distances ranging from ￡2￡(r)￡±￡μ￡2￡¨￡μ￡(c)to ￡2￡(r)291(5￡(c)|!￡(r)The approximately octahedral environment was completed by the oxygen atom of the coordinated water molecule with the Mn?O distance of ￡2￡(r)￡±￡?￡°￡¨￡μ￡(c)?￡(r)The hydrate water molecule is hydrogen-bonded to one of the O ato ms of free ClO ￡′￡- anion￡(r)
作者 寇会忠 高松
机构地区 清华大学化学系 北京大学化学与分子工程学院 北京大学化学与分子工程学院
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2002年第6期606-610,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金 博士后基金资助项目(No.29771001)。
关键词 晶体结构 锰(Ⅱ)配合物 叠氮酸根离子 crystal structure mangan ese(Ⅱ)complex azido ligand
分类号 O614.711 [理学—无机化学]
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参考文献16

  • 1(a)KOU Hui-Zhong(寇会忠),LIAO Dai-Zheng(廖代正)Wuji Huaxue Xuebao(Chin.J.Inorg.Chem.),1999,15.141;(b)Kou H.Z., Gao S., Bu W.M. et al J. Chem. Soc.,Dalton Trans., 1999, 2477.
  • 2Kou H. Z., Gao S., Ma B. Q., Liao D.Z. Chem. Commun.,2000, 713.
  • 3FU D. G., CHEN J., TAN X. S. et al Inorg. Chem., 1997,36, 220.
  • 4LU Tong-Bu(鲁统部),ⅪANG Hua(向华),LI Xiao-Yan(李晓燕)et al Gaodeng Xuexiao Huaxue Xuebao ( Chem. J.Chin. Universities), 2000, 21,187.
  • 5Shen Z., Zuo J. L., Chinnakali K. et al Acta Cryst., 1999,C55, 901.
  • 6Mikuriya M., Fujii T., Tokii T., Kawamori A. Bull. Chem.Soc. Jpn., 1993, 66, 1675.
  • 7Escuer A., Vicente R., Ribas J., Solans X. Inorg. Chem.,1995, 34, 1793.
  • 8Ribas J., Monfort M., Diaz C. et al Inorg. Chem., 1993,32, 3557.
  • 9(a)Kou H.Z., Liao D. Z., Cheng P. et al Synth. React.Inorg. Met. Org. Chem., 1998,28,405;(b)Cortes R., LezamA L., Pizarro L. et al Angew. Chem.Int. Ed. Engl., 1994, 33, 2488.
  • 10Hong C.S., Do Y. Angew. Chem. Int. Ed. Engl., 1999,38, 193.

同被引文献22

  • 1Shen Z, Zuo J L, Chinnakali K, et al. Diazidobis (1,10-phenanthroline-N, N')manganese ( Ⅱ ) [J]. Acta Crystallogr, 1999, C55: 901-903.
  • 2Bu P Y, Zhang L Z, Li L C, et al. Manganese (Ⅱ)-phenanthroline-azide compounds : Versatile precursors as ligands in designing heteropolymeric systems[J]. J Coord Chem, 2002, 55: 1 263-1 270.
  • 3Ni Z H, Kou H Z, Zheng L, et al. Assembly of azido-or cyano-bridged binuclear complexes containing the bulky [Mn(phen)2]^2+ building block: Syntheses, crystal structures, and magnetic properties[J]. Inorg Chem, 2005, 44: 4 728-4 736.
  • 4McCann S, McCannM, Casey R M T, et al. Syntheses and X-ray crystal structures of cis-[Mn(bipy)2Cl2· 2H2O · EtOH and cis- [Mn (phen)2Cl2 (bipy = 2,2'-bipyridine ; phen = 1, 10-phenanthroline) ; catalysts for the disproportionation of hydrogen peroxide[J]. Inorg Chim Acta, 1998, 279: 24-29.
  • 5Barnes D J, Chapman R L, Vagg R S, et al. Synthesis of novel his (amides) by means of triphenylphosphite intermediates[J]. J Chem Eng Data, 1978, 23: 349-350.
  • 6Ni Z H, Kou H Z, Zhang L F, et al. A cyano-bridged trimeric complex [Mn(CH3OH)2(H2O)2][-Fe(bpb)(CN)2]2 · 2H2O[bpb^2- is 1,2-bis(pyridine-2-carboxamido)benzenate][J]. Aeta Cryst, 2005, E61: m796-m798.
  • 7Ni Z H, Zhang L F, Ge C H, et al. Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterobimetallic trinuclcar Cr2^Ⅱ M nn complex based on K[Cr (salen)(CN)2] building bloek[J]. Inorg Chem Comm, 2008, 11: 94-96.
  • 8Ni Z H, Kou H Z, Zhang L F, et al. mer-[Fe(pcq)(CN)3]^- : A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear Fe2^Ⅱ Mn^2 complexes [pcq^- = 8- (pyridine-2-carboxamido)quinoline anion][J]. Inorg Chem, 2005, 44:9 631-9 633.
  • 9Kim J I, Yoon J H, Kwak H Y, et al. Crystal structures and magnetic behaviors of cyanido bridged dinuclear dimetallic systems involving 3d 3d or 3d-Sd metal centers[J]. Eur J Inorg Chem, 2008:2 756-2 763.
  • 10Armentano D, de Munno G, Guerra F, et al. 2,2r-Bipyrimidine-and 2,3 bis (2-pyridyl) pyrazine-containing manganese( Ⅱ ) compounds: Structural and magnetic properties[J]. Dalton Trans, 2003: 4 626-4 634.

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无机化学学报
2002年 第6期

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