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配合物[Mn(C_(13)H_8N_2OBr)_2(C_5H_5N)_2]·3C_5H_5N的结构与磁性研究 被引量:6

Study on Crystal Structure and Magnetic Susceptibility of [Mn(C_(13)H_8N_2OBr)_2(C_5H_5N)_2]·3C_5H_5N
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摘要 The complexMn £¨C £±£3 H £? N£2OBr £(c)£2£¨C£μH£μN£(c)2·3C5H5 N has been synthesized and characterized by X-Ray diffraction,IR and variable temperature(?10to ?£2£*£?K£(c)magnetic susceptibility£(r)X-Ray dif fraction result for the single crystal shows that the crysta l belongs to monoclinic,space group P21£ˉc£?a£1/2£±£(r)£°£1£?£1£¨£3£(c)nm£?b£1/2£2£(r)£°£1£°£3£¨£μ£(c)nm£?c£1/2£2£(r)£°£′£?£±£¨£?£(c)nm£?|?£1/2£1£*£(r)£3£?£?£¨£?£(c)£?V£1/2£′£(r)6&獭?£¨£2£(c)nm£3£?Z £1/2£′£?Dc£1/2£±£(r)47g·cm-3 。 The complexMn £¨C £±£3 H £? N£2OBr £(c)£2£¨C£μH£μN£(c)2·3C5H5 N has been synthesized and characterized by X-Ray diffraction,IR and variable temperature(?10to ?£2£*£?K£(c)magnetic susceptibility£(r)X-Ray dif fraction result for the single crystal shows that the crysta l belongs to monoclinic,space group P21£ˉc£?a£1/2£±£(r)£°£1£?£1£¨£3£(c)nm£?b£1/2£2£(r)£°£1£°£3£¨£μ£(c)nm£?c£1/2£2£(r)£°£′£?£±£¨£?£(c)nm£?|?£1/2£1£*£(r)£3£?£?£¨£?£(c)£?V£1/2£′£(r)6&獭?£¨£2£(c)nm£3£?Z £1/2£′£?Dc£1/2£±£(r)47g·cm-3 。
机构地区 西北大学化学系
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2002年第6期643-645,共3页 Chinese Journal of Inorganic Chemistry
基金 8陕西省教委专项基金资助课题(No.01JK078) 陕西省教委专项基金资助课题(No.01JK078)。
关键词 锰配合物 SCHIFF碱 晶体结构 合成 磁性能 锰酶 模拟酶 manganese complex Schiff base crystal structure synthesis ma gnetic properties
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