二氯·双(N,N-二乙基-2-辛硫基乙酰胺)合钯(Ⅱ)配合物的合成及其结构

SYNTHESIS AND STRUCTURE OF COMPLEX OF DICHLOROBIS (N,-N -DIETHYL-2-OCTYLTHIOACETAMIDO) PALLADIUM (Ⅱ)

在有机溶剂中合成了反式-[Pb(DEOTA)_2Cl_2],C_(28)H_(58)N_2O_(2)Cl_2S_2Pd,对配合物进行了组成分析、摩尔电导、差热-热重、紫外、红外等测试,并经X射线单晶结构分析,确定了配合物的结构.配合物晶体属单斜晶系,空间群C2/ca=32.513(9)(?),b=12.174(3)(?),c=9.798(4)(?),β=106.27(3)°,V=3722(1)(?)~3,Z=4,D_c=1.24g·cm^(-3).

The complex trans- [Pd (DEOTA)2C12] has been prepared in the organic solvent and characterized by elemental analysis, molar conductance, differential thermal and thermogravimetric analysis as well as UV and IR spectra. The molecular structure of the complex has been determined by four -circle X-ray diffractometer. The crystal belongs to space group C2/ c of monoclinic system.The crystal cell parameters are a = 32. 513(9)A, b= 12.174(3)A, c=9. 798(4)A, ·= 106.27(3) °, V= 2722(1)A3 and Z= 4.