芳香胺氮氧化物合贵金属配合物的研究——Ⅰ.2,2’-联喹啉—N,N’-二氧化物和金(Ⅲ)、铂(Ⅳ)及钯(Ⅱ)配合物的合成与表征

STUDIES ON THE NOBLE METAL COMPLEXES WITH AROMATIC AMINE N-OXIDEⅠ.SYNTHESES AND CHARACTERIZATION OF GOLD(Ⅲ),PLATINUM(Ⅳ)OR PALLADIUM(Ⅱ)COMPLEXES WITH 2,2'-BIQUJNOLINE-N,N'-DIOXIDE

合成了金(Ⅲ)、铂(Ⅳ)和钯(Ⅱ)与标题化合物形成的五种新配合物,研究了它们的组成与有关性质、可分为含氢键的离子缔合物和含金属一氧键的混配螯合物两类.

The five title complexes have been synthesized and characterized by elemental analyses, molar conductance, H-NMR, TR, UV, fluorescence spectra, DTA and X-ray powder difTraction. These complexea can be ciassifiod as two types. One is the ion-associated com- pounds containing hydrogen bond (Ⅰ -Ⅲ). The other is the mixed ligand chclates containing metal-oxygen bond (Ⅳ, Ⅴ).