氯离子对银胶中表面增强喇曼散射效应的影响

INFLUENCE OF CHLORIDE IONS ON SERS IN Ag SOL

讨论氯离子对银胶体系中对氨基苯甲酸(PABA)和吡啶(pyr)的表面增强喇曼散射(SERS)效应的影响。观察PABA在银胶中的SERS,氯离子的影响以及SERS强度-时间关系。发现氯离子的竞争吸附破坏PABA分子的类固相吸附并伴随着分子吸附状态的改变,从而导致SERS强度的减弱。研究PABA/银胶与pyr/银胶混合后添加氯离子的影响。同时观察氯离子对银胶中PABA和pyr光吸收的影响。发现氯离子对银胶中SERS的影响主要是化学增强。

The influence of chloride ions on SERS of PABA (p-aminobenzioc acid) and pyridine in Ag sol were discussed. SERS of PABA in Ag sol, the influence of chloride ions on and the time dependence of SERS intensities were obser ved. It was found that the decrease of SERS intensity was caused by that the solid like phase adsorption of PABA was destroyed and the molecular adsorption state was changed dut to the competitive adsorption of chloride ions. Besides, the influence of chloride ions on the time dependence of SERS intensities of a mixture of PABA/Ag sol and pyridine/Ag sol and on the light absorption of PABA and pyridine in Ag sol were studied. These experimtnts show that the influence of chloride ions on SERS in our system are mainly chemical.