摘要
Polysiloxane with fullerene moiety and its platinum complex have been prepared from (C\-2H\-5O)\-2CH\-3SiCH\-2CH\-2CH\-2NHCH\-2CH\-2NH\-2 via polymerization with (C\-2H\-6SiO)\-4 in the presence of (CH\-3)\-4NOH, followed by the reaction with C 60 , then the complex reacting with potassium chloroplatinite in acetone under argon atmosphere. The Pt complex is an effective catalyst for hydrosilylation of olefin with triethoxysilane. It is found that the regioselectivity increases remarkably by the introduction C 60 moiety.
Polysiloxane with fullerene moiety and its platinum complex have been prepared from (C\-2H\-5O)\-2CH\-3SiCH\-2CH\-2CH\-2NHCH\-2CH\-2NH\-2 via polymerization with (C\-2H\-6SiO)\-4 in the presence of (CH\-3)\-4NOH, followed by the reaction with C 60 , then the complex reacting with potassium chloroplatinite in acetone under argon atmosphere. The Pt complex is an effective catalyst for hydrosilylation of olefin with triethoxysilane. It is found that the regioselectivity increases remarkably by the introduction C 60 moiety.
出处
《分子催化》
EI
CAS
CSCD
北大核心
2002年第2期147-149,共3页
Journal of Molecular Catalysis(China)
基金
中国博士后科学基金
武汉市晨光计划
武汉大学自强基金资助项目
