摘要
The title compound, C31H30N3OPS3, crystallizes in monoclinic system, space group P21/n,with a = 11.839(7), b = 8.975(5), c = 29.15(2)? b = 100.07(1), V = 3049(3)?, Z = 4, Dc = 1.280g/cm3, Mr = 587.73, F(000) = 1232, m = 0.324mm-1, the final R = 0.0434 and wR = 0.1140 for 4787 observed reflections with I >2s(I). The title compound is a five-membered heterocycle containing a phosphorus, two nitrogen and two carbon atoms.The analysis result shows that the five-membered ring is nearly coplanar. The P(1)N(1) bond length(1.685? indicates the existence of pd?bond between N(1) and P(1) atoms of the title compound.
The title compound, C31H30N3OPS3, crystallizes in monoclinic system, space group P21/n,with a = 11.839(7), b = 8.975(5), c = 29.15(2)? b = 100.07(1), V = 3049(3)?, Z = 4, Dc = 1.280g/cm3, Mr = 587.73, F(000) = 1232, m = 0.324mm-1, the final R = 0.0434 and wR = 0.1140 for 4787 observed reflections with I >2s(I). The title compound is a five-membered heterocycle containing a phosphorus, two nitrogen and two carbon atoms.The analysis result shows that the five-membered ring is nearly coplanar. The P(1)N(1) bond length(1.685? indicates the existence of pd?bond between N(1) and P(1) atoms of the title compound.
基金
This project was supported by Foundation for University Key Teacher by the Ministry of Education
