摘要
The title complex [Ph 3Sn(CH 3OH)(terephthalate)(CH 3OH)SnPh 3]·2CH 3OH was synthesized by the reaction of Ph 3SnCl with terephthalate in the molar ratio of 2∶1 in methanol solution and characterized by elemental analysis, IR and 1H NMR spectra, and the crystal structure was determined by X ray single crystal diffraction study. The crystal belongs to monoclinic with space group P 2 1/ n , a =1.5199(5) nm, b =0.9000(3) nm, c =1.8206(6) nm, β=113.970(5)°, Z =2, V =2.2755 (13) nm 3, D c=1.413 g/cm 3, μ =1.146 mm -1 , F (000)=980, R =0.0353, wR =0.0606. In the crystals of complex, the tin atoms rendered five coordinate in a distorted tirgonal bipyramidal structure.
The title complex [Ph 3Sn(CH 3OH)(terephthalate)(CH 3OH)SnPh 3]·2CH 3OH was synthesized by the reaction of Ph 3SnCl with terephthalate in the molar ratio of 2∶1 in methanol solution and characterized by elemental analysis, IR and 1H NMR spectra, and the crystal structure was determined by X ray single crystal diffraction study. The crystal belongs to monoclinic with space group P 2 1/ n , a =1.5199(5) nm, b =0.9000(3) nm, c =1.8206(6) nm, β=113.970(5)°, Z =2, V =2.2755 (13) nm 3, D c=1.413 g/cm 3, μ =1.146 mm -1 , F (000)=980, R =0.0353, wR =0.0606. In the crystals of complex, the tin atoms rendered five coordinate in a distorted tirgonal bipyramidal structure.
基金
theNaturalScienceFoundationofShandongProvince (No.Y2 0 0 0B0 8)
