摘要
本文合成了四种新配合物:二氯化双苯甲醛缩氮基硫脲合铜(Ⅱ)(Cu~Ⅱ(Betsc—H)_2Cl_2),三氯化水杨醛缩氨基硫脲合铁(Ⅲ)(Fe~Ⅲ(Satsc—H_2)Cl_3,二氯化双对二甲氨基苯甲醛缩氨基硫脲合钴(Ⅱ)(Co~Ⅱ(Dmabtsc—H)_2Cl_2·H_2O)及双对硝基苯甲醛缩氨基硫脲合钴(Ⅱ)醋酸盐(Co~Ⅱ(Nitsc—H)(Nitsc)(Ac))。用元素分析和IR测定了化合物的组成,并进行了吸放O_2和CO的试验。
In this paper four new complexes: Bis(benzaldehydethiosemicarbazonato) copper(Ⅱ) dichloride ( Cu^1 (Betsc—H)_2Cl_2), Salicylalthiosemicar bazonato) ferric trichloride (Fe~Ⅱ(Satsc—H_2)Cl_3), Bis(pdimethyl-aminebenzaldehydethiosemicarbazonato) cobalt dichloride hydrate (Co~Ⅱ (Dmabtsc—H)_2Cl_2·H_2O) and his (p-nitrobenzaldethiosemicarbazonato) cobalt acetate (Co^1 (Nitsc-H(Nitsc) (Ac)) were synthesized and characterized by elemental analysis and IR Spectra. Their function of O_2 and Ce uptake or release have been tested.
出处
《新疆大学学报（自然科学版）》
CAS
1991年第4期78-80,50,共4页
Journal of Xinjiang University(Natural Science Edition)
关键词
铜
铁
钴
含硫Schiff碱
络合物
copper
Iron
cobalt, thiosemicarbazone, sulfur-containing Sehiff base, function of O_2 and CO reversible uptake or release.
