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氢酯基法合成3,5,5-三甲基己酸甲酯

Synthesis of 3,5,5-trimethyl hexanoic methylester by hydroesterfication of diisobutylene
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摘要 trimethyl hexanoic methylester was sythesised by hydroesterfication of branched olefin diisobutylene under mild conditions.With th changes of conditions we achieved rather good yield 78% (yield of 3,5,5 trimethyl hexanoic methylester) conversation of olefin 85% and good selectivity 93%,the optimum conditions are:reaction time 16h,pressure 8.0MPa,temperature 130℃. trimethyl hexanoic methylester was sythesised by hydroesterfication of branched olefin diisobutylene under mild conditions.With th changes of conditions we achieved rather good yield 78% (yield of 3,5,5 trimethyl hexanoic methylester) conversation of olefin 85% and good selectivity 93%,the optimum conditions are:reaction time 16h,pressure 8.0MPa,temperature 130℃.
出处 《化学研究与应用》 CAS CSCD 北大核心 2002年第3期302-303,共2页 Chemical Research and Application
关键词 氢酯基法 合成 3 5 5-三甲基己酸甲酯 氢酯基化反应 二异丁烯 合成香料 hydroesterfication 3,5,5 trimethyl hexanoic methylester diisobutylene
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