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不对称合成中手性磷配体催化剂的研究进展 (Ⅱ) (续完) 被引量：2

Progress of Chiral Phosphorus Ligands Catalysts in Asymmetric Synthesis
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摘要 评述了作为配体催化剂的手性三配位及四配位磷化合物的合成及其在某些不对称合成反应中的应用 This paper reviews the synthesis of some tri- and tetra- coordinate phosphorus compounds and their applications as ligands catalysts in the asymmetric synthesis.
作者 李康应 周正洪 唐除痴
机构地区 南开大学元素有机化学国家重点实验室元素有机化学研究所
出处 《化学研究》 CAS 2002年第2期49-58,共10页 Chemical Research
基金 国家自然科学基金项目 (No .2 9872 0 16)
关键词 不对称合成 手性磷配体 催化剂 研究进展 配体催化 手性氧化膦 手性磷酰胺 手性磷酰胺酯 手性磷酸三酯 asymmetric synthesis phosphorus ligands ligand catalysis.
分类号 O621.34 [理学—有机化学] O643.36 [理学—物理化学]
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参考文献27

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  • 2[2]Burns B, Studley J R, Wills M, et al. Chiral phosphinamides: new catalysts for the asymmetric reduction of ketones by borane[J]. J.Chem.Soc.,Perkin Trans I, 1998:1027-1038.
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  • 4[4]Yang Z, Zhou Z, Tang C. The synthesis of several chiral phosphorus reagents and their application in the asymmetric addition of aromatic aldehyde with diethylzinc[J].Main Group Metal Chem., 2001, 24(6):355-358.
  • 5[5]Reymond S, Brunnel J M, Buono G. Beneficial Effect of ortho-Methoxy Group in the Asymmetric Ring Opening of meso Epoxides with Silicon Tetrachloride Catalyzed by Chiral ortho-Methoxyphenyldiazaphosphonamide Lewis Bases[J]. Angew. Chem., Int. Ed., 2000, 39:2554-2557.
  • 6[6]Reymond S, Brunnel J M, Buono G. New development in the enantioselective ring opening of meso-epoxides by various chloride ion silicon sources catalyzed by an o-methoxyarydiazaphosphonamide lewis base[J]. Tetrahedron: Asymmetry, 2000, 11:4441-4445.
  • 7[7]Katsuhiko I, Yoshichika K, Takahashi M, Kishimoto S, Kobayashi Y. Asymmetric Allylation of Aromatic Aldehydes Catalyzed by Chiral Phosphoramides Prepared from (S)-Proline[J]. Tetrahedron 1997, 53(10):3513-3526.
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同被引文献105

  • 1曹书霞,刘金明,郭艳春,方芳,廖新成,赵玉芬.双分子缬氨酸氢膦烷构型的确定[J].波谱学杂志,2007,24(2):147-153. 被引量：2
  • 2Quin LD. A Guide to Organophosphorus Chemistry. New York: John Wiley & Sons, 2000.
  • 3Borner A. Phosphorus Ligands in Asymmetric Catalysis. Weinheim: Wiley-VCH, 2008.
  • 4Akiyarna T. Stronger Bronsted acids. Chem Rev, 2007, 107:5744-5758.
  • 5Denmark SE, Beutner GL. Lewis base catalysis in organic synthesis. Angew Chem Int Ed, 2008, 47, 1560-1638.
  • 6Zhou ZH, Wang YM, Tang CC. Nucleophilic tertiary phosphine organocatalysts in asymmetric reactions. Curr Org Chem, in press.
  • 7周正洪 马缚鹏 唐除痴.不对称合成中的手性磷辅助剂[J].化学通报(网络版),2000,0009.
  • 8Yang ZH, Zhou ZH, He K, Wang LX, Zhao GF, Zhou QL, Tang CC. Synthesis of some new chiral cyclic o-hydroxyarylphosphonodiamides as ligands for asymmetric silylcyanation of aromatic aldehydes. Tetrahedron: Asymm, 2003, 14:3937-3941.
  • 9He K, Zhou ZH, Wang LX, Li KY, Zhao GF, Zhou QL, Tang CC. Synthesis of a new chiral cyclic o-hydroxynaphthylphosphonodiamide and its application as ligand catalyst in asymmetric silylcyanation of aromatic aldehydes. Synlett, 2004, 1521-1524.
  • 10He K, Zhou ZH, Wang LX, Li KY, Zhao GF, Zhou QL, Tang CC. Synthesis of some new chiral bifunctional o-hydroxyarylphosphonodiamides and their application as ligands in Ti(IV) complex catalyzed asymmetric silylcyanation of aromatic aldehydes. Tetrahedron, 2004, 60: 10505- 10513.

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化学研究
2002年 第2期

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