配合物Zn(mnt)(Py)_2的合成、光谱表征和晶体结构(mnt^(2-)=maleonitriledithiolate)

Synthesis, Spectra Characterizations and Single Crystal Structure Determination for Complex Zn(mnt)(Py)_2

合成并应用元素分析、红外光谱和紫外 -可见光谱等技术表征了配合物 Zn( m nt)( Py) 2 。该配合物的单晶结构分析结果表明 :正交晶系 ,空间点群 P2 12 12 1。晶胞参数 a=8.6 470( 17) ,b=10 .5 78( 2 ) ,c=16 .896 ( 3) ,V =15 45 .4( 5 ) 3 ,Z=4。

The complex Zn(mnt)(Py) 2 has been synthesized and characterized by elemental analysis,IR and UV-visible spectra, respectively. The single crystal structure analysis of this complex has shown orthogonal system, space group P2 12 12 1, a = 8.6470(17) ,b = 10.578(2) ,c = 16.896(3) ,V = 1545.4(5)  3,Z=4.