新型后过渡金属铁系催化剂用于乙烯齐聚的研究
被引量:9
摘要
合成了两种新型后过渡金属铁系催化剂,并在助催化剂甲基铝氧烷(MAO)的作用下,对它们的乙烯齐聚行为进行了研究.发现该类催化剂具有高活性和对α-烯烃高选择性等特点,而且取代基、反应温度和Al/Fe摩尔比等因素对催化活性和产物分布有较大影响.
出处
《科学通报》
EI
CAS
CSCD
北大核心
2002年第10期755-757,共3页
Chinese Science Bulletin
基金
国家重点基础研究发展规划(批准号:G1999064800)
国家自然科学基金(批准号:29734141
50103012)
工程塑料国家重点实验室(SKLEP 0062)联合资助项目
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同被引文献44
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1WANG Hang, YAN Weidong, JIANG Tao, LIU Binbin, XU Wenqing, MA Jianjiang & HU YouliangState Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China,Graduate Student of.Ethylene oligomerization by novel iron(Ⅱ) diimine complexes/MAO[J].Chinese Science Bulletin,2002,47(19):1616-1618. 被引量:8
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2张志成,柯毓才,吕英莹,崔楠楠,胡友良.一种吡啶二亚胺类铁催化剂的合成及乙烯低聚研究[J].高分子学报,2005,15(2):191-196. 被引量:14
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引证文献9
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7隋军龙,赵晓,刘珺.基于二亚胺吡啶配体的铁系乙烯齐聚催化剂研究进展[J].石化技术,2024,31(7):1-5.
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8姜涛,贾辉,宁英男,曲广淼,丁伟.镍络合物/MAO催化乙烯与MMA共聚合[J].大庆石油学院学报,2003,27(3):38-40. 被引量:3
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二级引证文献31
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