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新型后过渡金属铁系催化剂用于乙烯齐聚的研究 被引量:9

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摘要 合成了两种新型后过渡金属铁系催化剂,并在助催化剂甲基铝氧烷(MAO)的作用下,对它们的乙烯齐聚行为进行了研究.发现该类催化剂具有高活性和对α-烯烃高选择性等特点,而且取代基、反应温度和Al/Fe摩尔比等因素对催化活性和产物分布有较大影响.
出处 《科学通报》 EI CAS CSCD 北大核心 2002年第10期755-757,共3页 Chinese Science Bulletin
基金 国家重点基础研究发展规划(批准号:G1999064800) 国家自然科学基金(批准号:29734141 50103012) 工程塑料国家重点实验室(SKLEP 0062)联合资助项目
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同被引文献44

  • 1WANG Hang, YAN Weidong, JIANG Tao, LIU Binbin, XU Wenqing, MA Jianjiang & HU YouliangState Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China,Graduate Student of.Ethylene oligomerization by novel iron(Ⅱ) diimine complexes/MAO[J].Chinese Science Bulletin,2002,47(19):1616-1618. 被引量:8
  • 2张志成,柯毓才,吕英莹,崔楠楠,胡友良.一种吡啶二亚胺类铁催化剂的合成及乙烯低聚研究[J].高分子学报,2005,15(2):191-196. 被引量:14
  • 3宁英男,刘晓瑜,王力搏,黄志军,姜涛.新型铁配合物/MAO催化乙烯低聚[J].化工进展,2006,25(6):680-683. 被引量:6
  • 4张宝军,邢立华,孟锐,姜涛,王延吉.氯化2-乙酰基-6-(2-甲基苯亚胺基)乙基吡啶铁/MAO催化乙烯齐聚的研究[J].石油学报(石油加工),2007,23(1):96-99. 被引量:5
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  • 10Small B L, Brookhart M. Iron-based catalysts with exceptionally high activities and selectivities for oligomerization of ethylene to linear α-Olefins. J Am Chem Soc, 1998, 120(28): 7143-7144

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