摘要
本文报导三甲基硅氧基亚磷酸酯(一种活性较高的磷硅试剂)与醛酮反应而获得十四个二乙基三甲硅氧基烃基膦酸酯。产物结构经IR,~1HNMR,^(31)PNMR,MS测试和元素分析表征;对反应机理作了初步讨论。
This paper reports a reaction between trimethylsiloxyphosphite (an active silicon-phosp-horus reagent) with aldehydes or ketones, and fourteen compounds of diethyl trimethylsilo-xyalkylphosphonates have been synthesized. The structures of the products were confirmedby IR,~1HNMR,^(31)PNMR,MS and elemental analysis measurements. The reaction mechanismis discussed.
出处
《应用化学》
CAS
CSCD
北大核心
1991年第1期33-37,共5页
Chinese Journal of Applied Chemistry
关键词
磷硅试剂
有机化合物
烃基膦酯类
silicon-phosphorus reagent
trimethylsiloxyphosphite
diethyl trimethylsilox-yalkylphosphonate
aldehyde
ketone
synthesis
