摘要
实验表明,Mn（Ⅲ）卟啉对理解血红蛋白的催化反应很有意义。Mn（Ⅲ）卟啉突出的性质是配位还原性,尤其与有机碱的反应。等研究了四苯基卟啉锰（Ⅲ）（TPPMn（Ⅲ）Cl）与有机碱的配位还原反应。本文部分作者曾研究过（β-硝基）四苯基卟啉锰（Ⅲ）,（（β-NO2）TPP Mn（Ⅲ）Cl）。
The title compound was extracted and synthesized from pig blood. Its coordination reduc-tion reactions with organic bases have been studied using spectral technique. The factorsaffecting the activity of coordination reduction were examined in comparison with otherporphyrin manganese (Ⅲ). The results demostrate that (a) the porphyrin ring with strongelectron-attracting groups is favor of the coordination reduction, (b) the namber of organicbase molecules participated in reaction depends on the structure of porphyrin, (c) orgapicbases studied gave the following reducing power: piperidine, n-propylamine>pyridine>imi-dazole.
出处
《应用化学》
CAS
CSCD
北大核心
1991年第4期67-70,共4页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金
关键词
锰卟啉二甲酯
有机碱
配位还原反应
Photodimethylesterprotoporphyrin manganese(Ⅲ)chloride
piperidine
n-propylamine
pyridine
imidazole
