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SO_4^(2-)/TiO_2-SiO_2固体超强酸的结构及其光催化性能 被引量:18

Structure and Photocatalytic Performance of SO_4^(2-)/TiO_2-SiO_2 Solid Superacid
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摘要 A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acidity of SO 2- 4/TiO 2 catalyst and its photocatalytic property for degradation of bromomethane was studied. The results showed that the specific surface area and amount of oxygen adsorption of catalyst were increased by addition of SiO 2, leading to the obvious increase on photocatalytic activity of SO 2- 4/TiO 2 SiO 2 catalysts and mineralization ratio of bromomethane. Comparing with SO 2- 4/TiO 2, the acidic strength and anti moisture ability of SO 2- 4/TiO 2 SiO 2 catalyst were decreased. A series of SO 2- 4/TiO 2 SiO 2 catalysts with different mass fractions of SiO 2 were prepared by sol gel method. The effect of adding SiO 2 on the crystal structure, specific surface area, oxygen adsorption, and acidity of SO 2- 4/TiO 2 catalyst and its photocatalytic property for degradation of bromomethane was studied. The results showed that the specific surface area and amount of oxygen adsorption of catalyst were increased by addition of SiO 2, leading to the obvious increase on photocatalytic activity of SO 2- 4/TiO 2 SiO 2 catalysts and mineralization ratio of bromomethane. Comparing with SO 2- 4/TiO 2, the acidic strength and anti moisture ability of SO 2- 4/TiO 2 SiO 2 catalyst were decreased.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2002年第7期1398-1400,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金 (批准号 :2 0 0 73 0 0 7 2 0 13 3 0 10 ) 福建省教育厅资助项目 (批准号 :K2 0 0 10 0 6) 高等学校骨干教师资助计划资助
关键词 结构 光催化性能 固体超强酸 SO4^2-/TiO2-SiO2 二氧化钛 二氧化硅 硫酸 Photocatalytic performance Solid superacid SO 2- 4/TiO 2 SiO 2
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  • 1唐新硕,王新平,金松寿.SO_4^(2-)/ZrO_2型超强酸酸中心形成机理研究[J].中国科学(B辑),1994,24(6):584-595. 被引量:42
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