线型1,2-邻二萘醌-1-肟(1-nqo)钌配合物的合成

Synthesis of Rod-like Ruthenium Complexes of 1,2-Naphthoquinone-1-oxime

报道了含C1 6长碳链线型 1,2 邻二萘醌 1 肟 (1 nqo)钌配合物trans ,cis 及cis ,cis [Ru(1 nqo) 2 (CO) (spy) ](3)及 (4 ) ,含C1 8长碳链线型 1 nqo钌配合物cis ,cis [Ru(1 nqo) 2 (CO) (opy) ](5 ) ,trans ,trans [Ru(1 nqo) 2 (opy) 2 ](6 )的合成 .利用红外、FAB质谱、核磁共振氢谱及紫外 -可见吸收光谱表征配合物的结构 ,利用1 H 1

By decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) axe synthesized as trans-, cis- and cis-, cis-[Ru(1-nqo)(2)(CO) (spy)] (3) and (4) which containing C-16 long alkyl chains in the molecules, cis-, cis-[Ru(1-nqo)(2)(CO)(opy)] (5) and trans-, trans-[Ru(1-nqo)(2)(opy)(2)] (6) which containing C-18 long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, H-1-H-1 COSY NMR and UV-visible spectra.