类钠离子激发态能级的计算

THE CALCULATIONS OF ENERGIES FOR EXCITED Na-LIKE ION

本文采用HFS法计算了Na、Mg^+、Al^(++)的ls^(2-)2P^6nl(n≤14.l≤7)所有激发态的能级。发现能级的计算值和实验值的相对误差先是随n的增大而迅速减小,然后缓慢变化并趋于一个相当小的“稳定值”。根据这一规律可以更准确地预言未知的较高能级值。

The HFS approximate method was used in calculating the energies of excited states for ls22s22P8nl (n≤l4,l≤5) configurations in Na, Mg4, Al++. These approximates for excited energies lead to the relative errors of theoretical and experimental that the more' n increases, the less the relative errors decreases rapidly, than change tardily and tend to guite small stable value. Accrding to this law, may predict unknown higher energy levels accurately.