摘要
本文用准经典动力学原理与方法,研究了H(~2S)-CC(X^1Σ^+_8)的绝热碰撞。发现在碰撞能低时可以形成长寿命络合物HCC,且此络合反应碰撞是无能的。此外,还研究了振转非弹性过程H+CC(V=J=0)→H+CC(V′,j′)的一般规律,并指出传能过程T(V)→R是主要的。
The present paper has studied the adiabatic collision of H(2S)+CC(X1∑g+) with the method of quasiclassical dynamics. It is found that in the lower relative kinetic energy region, it is possible to form the long-lived complex CCH and this reaction without threshold energy. General features of the inelastic process H++CC(V=J=0)→H+CC(V', J') have been discussed. It is pointed out that the main energy transfer processes are T(orV)→R.
出处
《原子与分子物理学报》
CAS
CSCD
北大核心
1991年第3期1901-1910,共10页
Journal of Atomic and Molecular Physics
基金
国家自然科学基金申请项目