新型钼磷酸有机衍生物(催化剂)的结构、制备和应用

THE STRUCTURE,PREPARATION AND APPLICATION OF NEW ORGANIC DERIVATIVES OF PHOSPHO-MOLYBDIC ACIDS(CATALYST)

摘要 [(EDTB)Me](CH3 COO) 2 和钼磷酸 (H3 PMo12 O4 0 )在无水乙醇中反应得到新型钼磷酸有机衍生物 [(EDTB)Me](HPM12 O4 0 ) ,Me为Cu、Co ,EDTB为N ,N ,N′ ,N′ -四 [(2 -苯并咪唑 )甲基 ]- 1,2 -乙二胺。测定了它的PMR、IR、紫外 -可见光谱。

H3PMo 12O 40),Me=Cu?Co,were prepared by the reaction of (CH 3COO) 2 with H 3PMo 12O 40 in absolute ethanol,in which EDTB is N,N,N′,N′-tetrakis[(2-benzimidazolyl)methyl]-1,2-ethylenediamine.The structure of the title compounds was characterized by PMR IR,UV-Vis,elemental analysis and crystal structure,and the catalytic activities of esterification of chloroacetic acid and pyrolytic elimination of cyclohexyl acetate were also determined,etc.