稀土镧金属富勒烯配合物的合成与表征

Synthesis and Characterization of Rare-earth Fullerene Complex

合成了稀土金属富勒烯配合物C60 [La(Gly) 2 ]2 (ClO4) 6,并用IR、UV VIS、元素分析等手段对其进行了表征 .实验结果表明通过取代反应 ,C60 和La(Gly) 4 Im(ClO4) 3 可以生成 η2 形式的稀土金属C60 配合物 .最后 。

New rare earth and buckminsterfullerene complex, C 60 [La(Gly) 2] 2(ClO 4) 6 has been synthesized, and characterized by UV VIS, IR and elemental analysis. The result shows that the rare earth fullerene complex of η 2 form can be synthesized through substituent reaction by using C 60 bonding to La(Gly) 4Im(ClO 4) 3 . In addition, the structure of the complex was supposed.