摘要
Though the fuel cell was invented by Grove in 1839,there are no commercially viable products at present.The development of fuel cells can be conveniently divided into three phases exploratory phase(1839-1967).The main emphasis of the work is to increase the area of the three phase interface at the electrode.The problem was solved by Bacon who invented the dual porosity,biporous nickel electrode.He demonstrated the first H 2/O 2 fuel cell(180℃,20atm).This cell was later improved and scaled up to power the Apollo lunar mission.However,the cost is too high for civilian applications and we come to the development phase (1967-2001).The main emphasis has been on the use of Teflon bonded electrodes and novel catalysts(PtRu,Pt/WO 3 and Pt Ru/WO 3 anode catalyst for the anodic oxidation of impure H 2 and methanol.In addition,the recent discovery of gadolinium doped ceria has reduced the operating temperature of solid oxide electrolytes to ～500℃ instead of 1?000℃.From 2001 onwards,we may be entering the breakthrough phase where the most favourable candidates are direct methanol vapor fuel cells and solid oxide electrolyte fuel cells.In the former case,there is a need to reduce the cross over of methanol to the cathode compartment and the development of air cathode catalyst which are less affected by methanol and in the latter case,there is a need to improve the activity of the anode and cathode catalysts.
Though the fuel cell was invented by Grove in 1839,there are no commercially viable products at present.The development of fuel cells can be conveniently divided into three phases exploratory phase(1839-1967).The main emphasis of the work is to increase the area of the three phase interface at the electrode.The problem was solved by Bacon who invented the dual porosity,biporous nickel electrode.He demonstrated the first H 2/O 2 fuel cell(180℃,20atm).This cell was later improved and scaled up to power the Apollo lunar mission.However,the cost is too high for civilian applications and we come to the development phase (1967-2001).The main emphasis has been on the use of Teflon bonded electrodes and novel catalysts(PtRu,Pt/WO 3 and Pt Ru/WO 3 anode catalyst for the anodic oxidation of impure H 2 and methanol.In addition,the recent discovery of gadolinium doped ceria has reduced the operating temperature of solid oxide electrolytes to ～500℃ instead of 1?000℃.From 2001 onwards,we may be entering the breakthrough phase where the most favourable candidates are direct methanol vapor fuel cells and solid oxide electrolyte fuel cells.In the former case,there is a need to reduce the cross over of methanol to the cathode compartment and the development of air cathode catalyst which are less affected by methanol and in the latter case,there is a need to improve the activity of the anode and cathode catalysts.
出处
《电池》
CAS
CSCD
北大核心
2002年第3期130-132,共3页
Battery Bimonthly
