摘要
Dibenzyltin bis(dithiotetrahydropyrrolocarbamate) was synthesized by the rea ction of dibenzyltin dichloride with dithiotetrahydropyrrolocarbamate. The compo und was characterized by elemental analysis, IR, 1H NMR and MS. and the crystal structure was determined by X-ray single crystal diffraction. The crystal bel ongs to orthorhombic with space group Pccn, a=2.1665(6)nm, b=0.9932(3)nm, c=1.19 79(3)nm,á=90a=90?=90穋m-3,ì (MoKá)=1.330mm-1,F(000)=1208,R1=0.0341, wR2=0.0627. In the crystals, the str uctures consist of discrete molecules in which the tin atom is six-coordinate in a distorted octahedron configuration. CCDC: 179919.
Dibenzyltin bis(dithiotetrahydropyrrolocarbamate) was synthesized by the rea ction of dibenzyltin dichloride with dithiotetrahydropyrrolocarbamate. The compo und was characterized by elemental analysis, IR, 1H NMR and MS. and the crystal structure was determined by X-ray single crystal diffraction. The crystal bel ongs to orthorhombic with space group Pccn, a=2.1665(6)nm, b=0.9932(3)nm, c=1.19 79(3)nm,á=90a=90?=90穋m-3,ì (MoKá)=1.330mm-1,F(000)=1208,R1=0.0341, wR2=0.0627. In the crystals, the str uctures consist of discrete molecules in which the tin atom is six-coordinate in a distorted octahedron configuration. CCDC: 179919.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2002年第8期819-822,共4页
Chinese Journal of Inorganic Chemistry
基金
教育部骨干教师基金
山东省自然科学基金资助项目(No.Y2000B08)
