N-对苯甲氧基-对-乙氧基-苯甲硫酰胺合铜(Ⅰ)的谱学研究

Studies on IR and NMR(~1H,^(13)C) Spectrum of Copper(Ⅰ) Complex with N-p-Methoxyphenyl-p-Ethoxyl-Benzosulfamide

以电化学方法合成了 N-对苯甲氧基 -对 -乙氧基 -苯甲硫酰胺合铜 ( )配合物 ,测定了该化合物的红外光谱和核磁共振谱 (1H、13 C)。结果表明 ,该化合物主要以硫酮形式与铜 ( )配位。

The copper(Ⅰ) complex with N-p-methoxyphenyl-p-ethoxyl-benzosulfamide (HL) were synthesized by electrochemical method.The IR and NMR( 1H, 13C) spectra of the compound show that the ligand of HL is coordinated to the copper(Ⅰ) with both S and N atoms as chelating agent in the formation of thioketone.