钙铝榴石-钙铁榴石的拉曼光谱特征

The Feature of Raman Spectra of Grossular-Andradite

通过对钙铝榴石 -钙铁榴石的拉曼光谱研究发现 ,从钙铝榴石到钙铁榴石 ,随着矿物结构中铁的含量的增加 ,他们的拉曼光发生规律性的变化 ,即所有的峰向低波数方向发生漂移 ;同时 ,由于铁含量的不同使得石榴石晶体结构中O -Si-O与O -Y -O之间的键角发生了一定的变化 ,在其拉曼光谱谱图上表现为铁的含量越高 ,[SiO4 ]四面体和Y -O八面体的两个弯曲振动峰分裂得越明显。

We have found that there are regularity changes in the Raman spectra of grossular-andradite as the rise of iron in the crystal structure from grossular to andradite after studying of Raman spectra of grossular-andradite, that is to say, their peaks shift to low wavenumber; At the same time , there are some changes in the bond angles of O-Si-O and O-Y-O:the higher of iron contents, the evidenter of splitting of two wind vibration peaks of SiO 4 tetrahedron and YO 6 octahedron.