环己基过氧化氢热分解过程中酸生成的研究

Study on the Acid Production in the Thermolysis of Cyclohexylhydrogenperoxide.

从理论上对环已酮 环己基过氧化氢 环己烷体系在过氧化物热分解时生成酸的途径进行了探讨 ,对含环己酮 环己基过氧化氢的环己烷溶液进行了环己基过氧化氢的热分解实验 ,得到了该体系生成酸的速度方程 ,并以此指导工业装置优化 ,取得良好效果。

The way of getting acid in the system of cyclohexanone-cyclohexylhydrogenperoxide-cyclohexane was investigted in theory,when peroxide was thermolysed.The experiment of cyciohexylhydroenperoxide being thermolysed in cyclohexane involving cyclohexanone was finished.And the growth rate equation of acid was obained.A good effect was getted when the growth rate equation of acid was used in optimuming industrial unit.