摘要
The multiphoton ionization dissociation of HFC 152a and HFC 134a under the irradiation of 355 nm and 266 nm was studied in this work. Their photolyzed products were analyzed by time of flight mass spectrum instrument. The photolyzed products of HFC 152a include H +( m/z =1), C +( m/z =12), CH + 3( m/z =15), C + 2( m/z =24), CF 2H +( m/z =51), and CF +( m/z =31), whereas there is no clear products for HFC 134a photolyzation. Further, the application prospects of HFC 152a and HFC 134a in refrigeration sector were also evaluated from the view point of environmental protection, synthesis conditions and usage performance. It is suggested that HFC 152a is a better alternative compared to HFC 134a in refrigeration sector.
The multiphoton ionization dissociation of HFC 152a and HFC 134a under the irradiation of 355 nm and 266 nm was studied in this work. Their photolyzed products were analyzed by time of flight mass spectrum instrument. The photolyzed products of HFC 152a include H +( m/z =1), C +( m/z =12), CH + 3( m/z =15), C + 2( m/z =24), CF 2H +( m/z =51), and CF +( m/z =31), whereas there is no clear products for HFC 134a photolyzation. Further, the application prospects of HFC 152a and HFC 134a in refrigeration sector were also evaluated from the view point of environmental protection, synthesis conditions and usage performance. It is suggested that HFC 152a is a better alternative compared to HFC 134a in refrigeration sector.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2002年第8期1504-1506,共3页
Chemical Journal of Chinese Universities
