摘要
合成并表征了系列含有酯基二茂铁亚胺环钯化合物.结果表明,该系列环钯催化剂在纯水或有机溶剂中均能高效催化Heck和Suzuki偶联反应.
Cyclopalladated ferrocenylimine dimers and cyclopalladated ferrocenylimine monomers were designed and prepared. They were characterized using 1H NMR, 13C NMR, and IR spectroscopies, and MS. The catalytic properties of these compounds in Heck and Suzuki coupling reactions in water or organic solvents were systematically investigated. The results showed that these catalysts could effectively catalyze Heck and Suzuki coupling reactions of aryl or heteroaryl halides in water or organic solvents.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2014年第7期1059-1067,共9页
基金
supported by the National Natural Science Foundation of China (20973157,J1210060)
the Research and Development Founda-tion of Zhengzhou University (2013xjxm020)~~
