期刊文献+

PY154-TiO2复合光催化剂的制备及其光催化性能

Preparation of PY154-TiO_2 composite photo-catalyst and their photocatalysis capacity
下载PDF
导出
摘要 以工业有机颜料C.I.颜料黄154(PY154)为敏化剂,采用溶剂热法制备了不同PY154含量的TiO2光催化剂(PY154-TiO2),并对其进行了表征。以可见光下对罗丹明B(RhB)的降解率为模型,考察了PY154-TiO2的光催化性能。结果表明,TiO2与PY154复合后,光响应范围由紫外区拓展到可见光区,其光催化活性明显高于TiO2。最后对催化剂的稳定性进行了研究,重复使用5次后其活性没有明显降低,说明PY154-TiO2具有较好的稳定性。 Using organic pigment Yellow 154 as sensibilizer,TiO2 photocatalyst(PY154-RiO2) with different PY154 contents has been prepared by solvothermal method,and the photocatalysis capacity is characterized.The photocatalysis capacity of PY154-TiO2 is evaluated under visible light irradiation,taking the degradation rate of Rhodamine B as model reaction.The results indicate that after TiO2 has combined with PY154,the photoresponse range extends from UV to visible light region,and its photocatalysis activity is significantly higher than TiO2.At the end,the stability of the catalyst is studied,and it is found that its activity is not significantly reduced after being used 5times repeatedly,which demonstrates that it has excellent stability and recyclability factors.
出处 《工业水处理》 CAS CSCD 北大核心 2014年第7期31-35,共5页 Industrial Water Treatment
基金 国家自然科学基金资助项目(21276027) 山东省高等学校科研计划项目(J12L64) 滨州市科技发展计划项目(2013ZC1602)
关键词 敏化剂 溶剂热法 罗丹明B 催化活性 sensitizer solvothermal method Rhodamine B photocatalytic activity
  • 相关文献

参考文献13

  • 1Gerischer H,Heller A. The role of oxygen in photooxidation of organic molecules on semiconductor particles [J]. J. Phys. Chem., 1991,95 ( 13 ) : 5261-5267.
  • 2Kormann C, Bahnemann D W, Hoffmann M R. Preparation and char- acterization of quantum-size titanium dioxide [J]. J. Phys. Chem., 1988,92(18) :5196-5201.
  • 3Cao J,Xu B Y, Luo B D,et al. Preparation,characterization and visible- light photocatalytic activity of AgI/AgCI/TiO2 [J]. Appl. Surf. Sci., 2011,257 : 7083-7089.
  • 4Wang Peng,Zakeeruddin S M, Moser J E,et al. A stable quasi-solid- state dye-sensitized solar cell with an amphiphilic ruthenium sensiti- zer and polymer gel electrolyte [J]. Nature Materials ,2003,2 (6) : 402-407.
  • 5Chen Chuncheng,Zhao Wei,Li Jingyi,et al. Formation and identifica- tion of intermediates in the visible-light-assisted photodegradation of sulforhodamine-B dye in aqueous TiO2 dispersion [J ]. Environ. Sci. Technol., 2002,36 ( 16 ) : 3604-3611.
  • 6张晓茹,林艳红,张健夫,何冬青,王德军.N掺杂TiO_2纳米粒子表面光生电荷特性与光催化活性[J].物理化学学报,2010,26(10):2733-2738. 被引量:48
  • 7Wang Peng, Huang Baibiao, Qin Xiaoyan, et al. A highly efficient and stable photocatalyst active under visible light [J ]. Angew. Chem. Int. Edit., 2008,47 ( 41 ) : 7931-7933.
  • 8Zhang Tianyong, ki Oyama T, Horikoshi S, et al. Photocatalyzed N- demethylation and degradation of methylene blue in titania disper- sions exposed to concentrated sunlight [J]. Solar Energy Materials and Solar Cells, 2002,73 (3) : 287-303.
  • 9Fox M A,Dulay M T. Heterogeneous photocatalysis [J]. Chem. Rev., 1993,93 ( 1 ) : 341-357.
  • 10Zhao Dan,Chen Chuncheng, Wang Yifeng,et al. Enhanced photoca- talytic degradation of dye pollutants under visible irradiation on A1 ( Ⅲ ) -modified TiO2:structure, interaction, and interracial electron transfer [ J ]. Environ. Sci. Technol., 2008,42 ( 1 ) : 308-314.

二级参考文献30

  • 1崔文权,冯良荣,徐成华,吕绍洁,邱发礼.纳米Pt/TiO_2催化剂上气相CH_3OH光催化分解制氢反应的研究[J].化学学报,2005,63(3):203-209. 被引量:17
  • 2华南平,吴遵义,杜玉扣,邹志刚,杨平.Pt、N共掺杂TiO_2在可见光下对三氯乙酸的催化降解作用[J].物理化学学报,2005,21(10):1081-1085. 被引量:46
  • 3Mor,G.K.;Shankar,K.;Paulose,M.;Varghese,O.K.;Grimes,C.A.Nano Lett.,2006,6:215.
  • 4Konstantinau,I.K.;Albanis,T.A.Appl.Catal.B,2003,42:319.
  • 5Sakthivel,S.;Kisch,H.Angew.Chem.Int.Edit.,2003,42:4908.
  • 6Asahi,R.;Morikawa,T.;Ohwaki,T.;Aoki,K.;Taga,Y.Science,2001,293:269.
  • 7Lin,Z.S.;Orlov,A.;Lambert,R.M.;Payne,M.J.Phys.Chem.B,2005,109:20948.
  • 8Kuroda,Y.;Mori,T.;Yagi,K.;Makihata,N.;Kawahara,Y.;Nagao,M.;Kittaka,S.Langmuir,2005,21:8026.
  • 9Kisch,H.;Sakthivel,S.;Janczarek,M.;Mitoraj,D.J.Phys.Chem.C,2007,111:11445.
  • 10Yang,K.S.;Dai,Y.;Huang,B.B.J.Phys.Chem.C,2007,111:12086.

共引文献59

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部