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Effects of Temperature and Concentration on the Rheological Behavior of Polyacrylamide-Based Polymers

Effects of Temperature and Concentration on the Rheological Behavior of Polyacrylamide-Based Polymers
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摘要 Polymers are high molecular weight molecules that provide high viscosity at low concentrations to the media they are inserted. In the oil industry, they are used for enhanced oil recovery and for drilling fluids, where its viscosity is an important factor for a greater efficiency. From all the polymers used by industry, the polyacrylamide and the biopolymer xantham gum are those, which appear significantly in those applications. Taking that into consideration, this work intends to study the effects of the physical, chemical and structural parameters of those polymers in their rheological behaviour, by varying their concentrations from 400 ppm to 2,000 ppm and their temperatures from 298 K to 328 K, which are values similar to those found in the field. For that, a Brookfield Viscometer-Brookfield Engineering Labs rheometer was used. The results acquired showed that the increase on the polyacrylamides ionicity generates and increase on the medium viscosity. For the temperature, its increase causes a reduction of viscosity for the low ionicity polyacrylamides, while increases the viscosity for the high ionicity ones. In the comparative study between xantham gum and polyacrylamides, it was possible to notice that, even though the biopolymer is more complex, its viscosity still is lower when compared to the polyacrylamides.
出处 《Journal of Chemistry and Chemical Engineering》 2014年第5期535-543,共9页 化学与化工(英文版)
关键词 Rheology of polymer POLYACRYLAMIDE biopolymer. 生物聚合物 流变行为 低浓度 丙烯酰胺基 温度 聚丙烯酰胺 高分子量 粘度计
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