摘要
水热法合成了以对苯二甲酸和柠檬酸为配体的钕的配合物。通过红外、紫外、荧光、循环伏安法、热重分析对其进行了表征。结果表明,配合物在372 nm处具有较强的荧光发射峰,在-0.3~0.4 V的电势范围内研究配合物的电化学性质,研究结果表明,配合物在此电势范围内具有电化学活性。
The research of a novel neodymium (Ⅲ) complex synthesized with terephthalic acid and citric acid as ligands by hydrothermal method was introduced.According to the infrared , ultraviolet , fluorescence and cyclic voltammetry, thermogravimetric analysis on the characterization , the results indicated that the complex had strong fluorescence emission peak at 372.0 nm.In the potential range of -0.3 ~0.4 V, electrochemical properties of the complex were researched , and it showed obvious electrochemical activity within the scope of this potential.
出处
《广州化工》
CAS
2014年第13期59-60,63,共3页
GuangZhou Chemical Industry
基金
湖北省自然科学基金资助项目(2012FFB00205)
全国大学生创新训练项目(201210512054)
关键词
对苯二甲酸
钕
配合物
电化学
neodymium
terephthalicacid
complex
electrochemical properties