摘要
介绍在无水无氧条件下,非质子溶剂体系中质解席夫碱酚羟基质子的方法,即主要利用金属有机试剂(M-C)、金属氢化物试剂(M-H)、活泼金属试剂(M)、金属氮化物试剂(M-N)和金属芳氧(烷氧)试剂(M-O)与含酚羟基的席夫碱反应,生成含M-O(Ar)键的席夫碱金属配合物.同时指出了某些质解反应中出现的一些异常现象.
Proton-elimination reaction methods of phenolic hydroxyl on Schiff-base are introduced in anhydrous,oxygen-free and aprotic solvent system.Metal Schiff-base complexes containing the M-O(Ar)bond can often be synthetized by the method above.Meanwhile,the abnormal phenomena in some methods are pointed out.Common proton-elimination reagents include metal organic reagents(M-C),metal hydride reagents(M-H), active metal reagents(M),metal nitride reagents(M-N)and metal aromatic oxygen(alkoxy)reagents(M-O).
出处
《苏州市职业大学学报》
2013年第4期59-62,共4页
Journal of Suzhou Vocational University
基金
苏州市职业大学博士启动基金资助项目(2009BS01)
关键词
席夫碱
酚羟基
质解
Schiff-base
Phenolic Hydroxyl
proton-elimination