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Synthesizes and Characterization Studies of Some Metal Ion Complexes with EOSBE and MOSBE

Synthesizes and Characterization Studies of Some Metal Ion Complexes with EOSBE and MOSBE
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摘要 This work includes synthesis of 2,2'-(5,5'-(ethane-1,2-diyl)bis(1,3,4-oxadiazole-5,2diyl))bis(sulfanediyl)dibenzenamine (EOSBE) and 2,2'-(5,5'-methylenebis(1,3,4-oxadiazole-5,2-diyl)bis(sulfanediyl))dibenzenamine (MOSBE). All synthesized ligands were characterized by IR, ^1H-NMR, ^13C-NMR, UV-visible spectroscopies and molar conductivity. A series of complexes with a general formula [M2LCl4]. Where M(Ⅱ) = Co, Ni, Cu and Zn; L = EOSBE and MOSBE were synthesized in basic media using KOH solution. In these complexes both ligands are bidentate ligands coordinated through sulfur and nitrogen. All complexes have been characterized by IR-spectra, UV-visiblc spectra, conductivity and magnetic susceptibility.
出处 《Journal of Food Science and Engineering》 2014年第3期160-165,共6页 食品科学与工程(英文版)(美国)
关键词 SYNTHESIS CHARACTERIZATION sulfanediyl metal ion complexes. 离子配合物 13C-NMR 摩尔电导率 表征 金属 1H-NMR 可见光谱 IR光谱
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