摘要
In order to improve the property of traditional Ce-based conversion coatings, Ce-silane-ZrO2 composite coatings were successfully prepared on 1060 aluminum. The microstructure, chemical element composition and corrosion resistance of Ce-based conversion coatings and Ce-silane-ZrO2 composite coatings were investigated by SEM, AFM, XPS and EIS analyses. Stacking structure of the composite coating can be observed. The inner layer of the composite coatings mainly consists of oxide and hydroxide of Ce（Ⅲ）, and the silane network is composed of the outer layer together with a small amount of Ce（Ⅳ） hydroxide. By adding silane and ZrO2 nanoparticles into Ce-based conversion coatings, the porosity and the micro cracks of the coatings decrease apparently accompanying with the improvement of the corrosion resistance.
为了改善传统稀土转化膜的性能,运用浸泡法在铝表面制备Ce-硅烷-ZrO2复合膜。运用SEM、AFM、XPS和EIS等技术手段对复合膜层的微观形貌、化学组成和电化学性能进行研究,并与Ce转化膜进行比较。Ce-硅烷-ZrO2复合膜层表面呈堆砌结构,膜内层主要由Ce(III)的氧化物和氢氧化物构成,而膜外层的主要成分是硅烷偶联聚合而成的大分子网状结构。与Ce转化膜相比,加入硅烷和ZrO2纳米微粒后,复合膜表面的微孔和裂纹都明显减少,且耐蚀性能有了明显的改善。
基金
Project(51172217)supported by the National Natural Science Foundation of China
Project(2010GGX10310)supported by Shandong Science and Technology Program,China
Project(10-3-4-1-jch)supported by Science and Technology Program on Basic Research Project of Qingdao,China
Project(4500-841313001)supported by Fundamental Research Funds for the Central Universities,China
