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多元醇对PET降解机理的研究 被引量:1

The Research on the Degradation Mechanism of PET in Polyhydric Alcohol
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摘要 采用几种不同离子液体作为催化剂,采用微波辅助醇解法,研究废弃聚酯PET在不同多元醇(乙二醇,丙三醇,1,4-丁二醇)中的醇解机理并利用红外光谱初步判定醇解产物结构,综合三种表征,最终得到不同多元醇醇解PET的醇解机理.与此同时微波反应大大缩短了解聚时间,提高了解聚反应的效率. Using several different ionic liquids as catalyst, the waste PET alcoholysis mechanism in different polyhydric Alcohol is studied by the microwave alcoholysis product is determined by IR spectrum. The d is gained. At the same time, by the microwave reaction, the efficiency of the polymerization. -assisted alcoholysis method, and the structure of egradation mecharism of PET the time to understand gather in polyhydric alcohol is shorten to improve
机构地区 哈尔滨师范大学
出处 《哈尔滨师范大学自然科学学报》 CAS 2014年第4期75-79,共5页 Natural Science Journal of Harbin Normal University
基金 2013年哈尔滨师范大学大学生创新创业训练计划"废旧聚酯材料的再资源化"项目(201310231017)
关键词 微波 解聚反应 Microwave Depolymerization reaction
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