含磺酸基配合物结构的研究进展

Research Progress in Structure of Complexes Containing Sulfonate Groups

含磺酸基有机配体的配合物种类繁多,其中主要包括简单磺酸配合物、芳香环磺酸配合物、杂环芳香磺酸配合物和Schiff碱磺酸配合物等。其空间结构多种多样,比如一维链状结构、二维层状结构和三维网状结构。该类配合物具有优异的物理和化学性质,在众多领域里显示出广阔的应用前景。合成结构新颖、组成多样的新型磺酸基配合物及其应用研究已经成为配位化学领域的研究前沿和热点之一。综述了含磺酸基有机配体配合物的分类以及结构研究进展,探讨了该研究领域亟待解决的问题以及今后可能的发展前景。

The complexes containing organic ligands with sulfonic groups have a great variety of species, mainly including simple sulfonic complexes, sulfonic complexes with an aromatic ring, sulfonic complexes with heter-aromatie ring, sehiff base sulfonic complexes, etc. They have a variety of spatial structure, such as a one-dimensional chain structure, two-dimensional layered structure and the three-dimensional network structure. The kind of complexes has excellent physical and chemical properties, and shows good applications prospect in so many areas. The synthesis of sulfonic complexes with novel structures and components, and their applications have become one of the forefront and hot topics in the area of coordination chemistry. The classification and structure of the complexes containing organic ligands with sulfonic groups were summarized. The problems to be solved and possible future prospect of development were discussed.