环氧大豆油制备研究进展

Progress in Preparation of Epoxy Soybean Oil

叙述环氧大豆油制备的研究进展,包括羧酸催化环氧化和非羧酸催化环氧化。其中羧酸催化环氧化包括:羧酸催化环氧化,浓硫酸与羧酸联合催化环氧化、对甲苯磺酸与羧酸联合催化环氧化、酸性离子交换树脂与羧酸联合催化环氧化、固体强酸与羧酸联合催化环氧化、酶与羧酸联合催化环氧化,硫酸铝与羧酸联合催化环氧化;非羧酸催化环氧化包括:过渡金属配合物催化环氧化、磷钨杂多酸(盐)催化环氧化和相转移催化环氧化。

Progress of epoxy soybean oil preparation methods were described, including carboxylic acid catalytic epoxidation and Non-acid catalytic epoxidation, the carboxylic acid catalytic epoxidation include; Carboxylic acid catalytic epoxidation, United catalytic epoxidation of concentrated sulfuric acid and Carboxylic acid, United catalytic epoxidation of p-toluenesulfonic acid and Carboxylic acid, United catalytic epoxidation of acid ion exchange resin and Carboxylic acid, United catalytic epoxidation of solid strong acid and Carboxylic acid, United catalytic epoxidation of enzymes and Carboxylic acid, United catalytic epoxidation of aluminum sulfate and Carboxylic acid; non-acid catalyzed epoxidation include; transition metal complex catalytic epoxidation, phosphotungstic acid （salt） catalytic epoxidation and phase transfer catalytic epoxidation.