摘要
采用超声辐射，以对叔丁基杯[n]芳烃为原料，先通过逆Fridel—Crafts反应脱去叔丁基，得到杯[n]芳烃，进一步磺化，可高效制得磺化杯[n]芳烃。两步反应约0．5—1h即可完成，收率可达到90％以上。该方法较传统加热方法，操作简单，反应时间大大缩短。
Under ultrasonic irradiation,p-sulfonic acid calixarene could he efficiently synthesized by using tert-hutyi calix [ n] arene as material by debutylation with AlCl3 in toluene, then sulfonation with concentrated sulfuric acid. The results showed that the reaction can be finished in only 0. 5 - 1 h and the yield was achieved to higher than 90%. The method has advantages of easy operation, short reaction time reducing and high yields.
出处
《化学试剂》
CAS
CSCD
北大核心
2014年第8期755-757,共3页
Chemical Reagents
基金
江苏省高校自然科学基金资助项目(12KJB-350005)
江苏省大学生科技创新课题资助项目(2011-1000)
江苏高校优势学科建设工程资助项目
关键词
超声波辐射
去叔丁基化
磺化杯芳烃
快速合成
ultrasonic irradiation
debutylation
p-sulfonic acid calixarene
rapid synthesis
