1,4-萘二酸银配合物的合成与性质表征

Synthesis, Structure and Properties of Silver(I) Complexes With 1,4-Naphthalenedicarboxylic Acid Ligand

简要概述了1,4-萘二酸银配合物的合成和晶体结构的分析,并对银配合物的研究进展进行了概括。通过溶液法以银盐,1,4-萘二酸和含氮杂环配体合成两个配位聚合物:[Ag4(1,4-ndc)(5-methy-2-apy)4]n(1)、[Ag4(1,4-ndc)2(5-methy-2-apy)4]n·0.5 nCH3CN(2)。对这两个配合物进行了红外、X-单晶衍射等结构表征,并对配合物进行了热重的测量。

Two new silver（I） coordination polymers, namely [Ag4（1,4-ndc）（5-methy-2-apy）4]n（1）,[Ag4（1,4-ndc）2（5-methy-2-apy）4]n·0.5nCH3CN（2） [1,4-H2ndc = 1,4-naphthalenedicarboxylic acid,5-methy-2-apy = 2-amino-5-methylpyridinee] were synthesized by solution reactions of AgNO3 with 1,4-naphthalenedicarboxylic acid and various heterocyclic N-donor ligands at room temperature. These complexes were characterized by FT-IR spectra,TGA and single-crystal X-ray diffraction.