烯烃羰基合成铑催化剂进展及应用

The Application and Progress of Rhodium Catalyst in the Carbonyl Synthesis

铑催化剂的研究开发促进了烯烃羰基合成工业的发展,综述了近年来铑催化剂的发展:一是高效膦配体的开发;二是水/有机两相铑催化剂的设计合成,包括水溶性铑催化剂和固载型铑催化剂的开发。并列举了铑膦催化剂在工业中的应用情况。

The research and development of rhodium catalysts promoted the progress of olefin carbonyl syn- thesis industry. This paper reviews the research progress of rhodium catalysts in recent years, which in- cluding the development of efficient phosphine ligands and the design and synthesis of aqueous/organic bi- phasic rhodium catalysts. The biphasic rhodium catalysts include water-soluble rhodium catalyst and sup- ported rhodium catalyst. And the application of rhodium-phosphine catalysts in industry is also mentioned.