Nucleophilic Polymer-supported Tertiaryphosphine Organocatalysis：[3＋2] Annulation Reaction of Alkyl 2-Butynoates with Activated Alkenes

Nucleophilic Polymer-supported Tertiaryphosphine Organocatalysis：[3＋2] Annulation Reaction of Alkyl 2-Butynoates with Activated Alkenes

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摘要 JandaJel resin-supported triphenylphosphine（JJ-TPP）,was used as an effective organocatalyst for the [3＋2] annulation reaction of alkyl 2-butynoates with electron-deficient alkenes to afford the corresponding cyclopentenes in 40％-68％ isolated yields.JJ-TPP was reused after simple filtration and vacuum drying. JandaJel resin-supported triphenylphosphine（JJ-TPP）,was used as an effective organocatalyst for the [3＋2] annulation reaction of alkyl 2-butynoates with electron-deficient alkenes to afford the corresponding cyclopentenes in 40％-68％ isolated yields.JJ-TPP was reused after simple filtration and vacuum drying.

作者 LIU Hailing

机构地区 Analytical and Testing Center

出处《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2014年第4期593-595,共3页 高等学校化学研究（英文版）

关键词 ORGANOCATALYSIS Polymer-supported tertiaryphosphine [3＋2] Annulation reaction Organocatalysis Polymer-supported tertiaryphosphine [3＋2] Annulation reaction

分类号 TQ324.9 [化学工程—合成树脂塑料工业] O632.12 [理学—高分子化学]

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Nucleophilic Polymer-supported Tertiaryphosphine Organocatalysis：[3＋2] Annulation Reaction of Alkyl 2-Butynoates with Activated Alkenes

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