摘要
以(Mg0.8Zn0.2)TiO,(MZT)为原料,采用加入高电介质材料Ba4Nd28/3T18O54zBi2O3(BNT)制备微波电介质陶瓷0.7(Mg08Zn02)T103·0.3{Ba4Nd2Ⅳ3Ti18054·zBi203I(z=0.15,0.18,0.2),以提高MZT的介电性能。掺入Bi3+可以降低烧结温度,从而可以在低烧结温度((1200-1230%)下制取MZT和BNT的合成材料。通过对介电性能、密度、XRD和SEM测试所获得的陶瓷可以发现,掺入Bi3+数量的多少和结烧温度的高低会影响到陶瓷的结构和性能,结果说明,当z=0.18,0.7(Mgn8znn2)Ti03·0.3{Ba4NdzsnTil8054·zBi203}的结烧温度为1230℃时,可以获得很好的介电性能:εr=35.56,Qf=5811GHz,TF=-3.225ppm/℃。
The (MgosZna2)TiO3 (MZT) as the foundation is Ba4NdTizsO54 zBi203 (BNT) to preparation microwave mainly studied to join high dielectric material dielectric ceramic 0.7(Mgo.sZno.2)TiO3.0.3 {Ba4Nd28/3TilsO54·zBi203}(z=O.15, 0.18, 0.2) to improve dielectric properties of MZT. While Bi3+ could lower the sintering temperature to make MZT and BNT composite in a low sintering temperature (1200-1 230 ℃) . According to the results of the dielectric properties, density, XRD and SEM tests of the obtained ceramics, we can find out that the amount of doped Bi3+ and the sintering temperature affected the structure and properties of the ceramics. The results show that when z=0.18, 0.7 (Mg0sZn zBi203} sintering at 1230℃ can get good dielectric properties: εr=35.56,Qf=5811GHz,TF=-3.225ppm/℃.