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手性硫脲催化剂不对称催化反应及氢键活化作用研究

Chiral Thiourea Derivatives in Asymmetric Catalysis and Its Hydrogen Bond Activation Theory
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摘要 手性硫脲在不对称催化反应中是一类典型的双功能有机小分子催化剂.文章综述了对称催化反应中手性硫脲的氢键活化理论模型研究现状,重点阐述了手性硫脲催化剂对底物的氢键活化作用的影响规律,并对未来的研究方向提出了观点. Chiral thiourea derivative is one of typical bifunctional organic small catalyst in asymmetric catalysis. The research of hydrogen activation theory of chiral thiourea derivative for asymmetric catalysis is reviewed, highlighting the structural characters of chiral thiourea and the influence on the hydrogen bonding activation for substrate. The possible research tendency in this field is also discussed.
作者 陈盛楷 买昊 赵志伟 赵博文 刘颖 鲜亮
机构地区 西北民族大学化工学院
出处 《西北民族大学学报（自然科学版）》 2014年第1期17-21,共5页 Journal of Northwest Minzu University(Natural Science)
基金 国家大学生创新创业训练计划项目(201310742005) 中央高校基本科研业务费专项资金项目(ZYZ2012066) 2012年度留学人员科技活动项目(2012-258)
关键词 手性硫脲 不对称催化 氢键活化 Chiral thiourea Asymmetric catalysis Hydrogen bond activation theory
分类号 O643.32 [理学—物理化学]
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参考文献16

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西北民族大学学报（自然科学版）
2014年 第1期

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